84118-64-9

Upstream product

• 16035-11-3 3-(3-methylphenyl)propargyl alcohol 
• 74-88-4 methyl iodide 
• 625-95-6 3-Iodotoluene 
• 627-41-8 propargyl alcohol methyl ether 

Downstream Products

• 1188516-77-9 C₂₈H₄₄OSi 
• 1188516-88-2 C₂₈H₄₄OSi 
• 1343516-28-8 3-(1-methoxy-3-m-tolylprop-2-ynyl)-3-methylpentane-2,4-dione 
• 1343516-43-7 (E)-2-(methoxymethyl)-1,5-di-m-tolylpent-2-en-4-yn-1-one 
• 84118-68-3 3,3-bis(3-methylphenyl)-2-propenal 

Relevant academic research and scientific papers

Iron(II) chloride catalyzed alkylation of propargyl ethers: Direct functionalization of an sp3 C-H bond adjacent to oxygen

Iron(II) chloride catalyzed direct alkylation of sp3 C-H bond adjacent to oxygen in propargyl ethers has been accomplished by the use of 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as oxidant under mild reaction conditions. The reaction proceeded smoothly with a variety of 1,3-diketones leading to -dicarbonyl ether in moderate yields. In the absence of 1,3-diketones, ynenones were produced by the use of iron(III) chloride and DDQ. Georg Thieme Verlag Stuttgart - New York.

Palladium-Catalyzed Acylation of Unsaturated Halides by Anions of Enol Ethers

Zinc salts of enol ether anions are coupled to aryl and alkenyl halides by using palladium catalysts, effecting a direct acetylation of aryl and alkenyl halides.Zinc salts of allenic ethers are coupled with aryl and alkenyl halides under similar conditions to give α,β-unsaturated ketones, the allenic ether serving as a source of the acryloyl group.Allenic ethers were γ arylated in a palladium-catalyzed coupling with aryl halides to give β,β-diaryl-α,β-unsaturated aldehydes.