84207-52-3Relevant academic research and scientific papers
Phenyl 2-Deoxy-2-iodo-1-thio-glycosides: New Glycosyl Donors for the Stereo-selective Synthesis of 2-Deoxy-oligosaccharides
Arnés, Xavier,Díaz, Yolanda,Castillón, Sergio
, p. 2143 - 2146 (2003)
Phenyl 2-deoxy-2-iodo-1-thioglycosides, prepared from simple pentoses by olefination and iodine-induced cyclization, have proved to be efficient glycosyl donors for the stereoselective synthesis of 2-deoxy-2-iodo- oligosaccharides, which are precursors of
Bronsted Acids of Anionic Chiral Cobalt(III) Complexes as Catalysts for the Iodoglycosylation or Iodocarboxylation of Glycals
Wang, Rui,Wu, Wen-Qiang,Li, Na,Shen, Jia,Liu, Kun,Yu, Jie
supporting information, p. 1077 - 1084 (2019/05/24)
Bronsted acids of anionic chiral Co(III) complexes were found to act as efficient phase-transfer catalysts for the diastereoselective iodoglycosylation or iodocarboxylation of glycals with a variety of alcohols or carboxylic acids, respectively, with N -iodosuccinimide as the iodo cation source. The corresponding 2-deoxy-2-iodoglycosides, including monosaccharides and disaccharides, and 2-deoxy-2-iodoglycosyl carboxylates, which are of high synthetic and biological importance, were obtained in high yields (up to 88%) with good diastereoselectivities (up to 9:1 dr).
Glycosylations of Glycals using N-Iodosuccinimide (NIS) and Phosphorus Compounds for Syntheses of 2-Iodo- and 2-Deoxyglycosides
Kimura, Tomoya,Takahashi, Daisuke,Toshima, Kazunobu
, p. 9552 - 9562 (2015/10/12)
The glycosylations of glycals and alcohols using N-iodosuccinimide (NIS) and a catalytic amount of PPh3 effectively proceeded under mild conditions to provide the corresponding 2-deoxy-2-iodoglycosides in high yields. The reactivity of the iodo
HIGHLY STEREOSELECTIVE SYNTHESIS OF α-D-GLUCOPYRANOSIDES BY THE N-IODOSUCCINIMIDE-PROMOTED INTERNAL CYCLIZATION
Suzuki, Keisuke,Mukaiyama, Teruaki
, p. 1525 - 1528 (2007/10/02)
Highly stereoselective cyclizations of hydroxy enol ethers are effected by N-iodosuccinimide to result in the exclusive formation of 2'-deoxy-2'iodo-α-D-glucopyranosides.An analog of glycolipid is also successfully synthesized according to the present met
