84466-74-0Relevant academic research and scientific papers
SYNTHETIC CONTROL LEADING TO CHIRAL COMPOUNDS
Mukaiyama, Teruaki,Iwasawa, Nobuharu,Stevens, Rodney W.,Haga, Toru
, p. 1381 - 1390 (2007/10/02)
A highly diastereoselective cross aldol reaction is developed using divalent tin enolates formed from stannous trifluoromethanesulfonate and carbonyl compounds.The reaction is extended to a highly enantioselective cross aldol reaction employing chiral dia
STANNOUS TRIFLATE: A FACILE CROSS-ALDOL REACTION BETWEEN TWO KETONES VIA DIVALENT TIN ENOLATES
Stevens, Rodney W.,Iwasawa, Nobuharu,Mukaiyama, Teruaki
, p. 1459 - 1462 (2007/10/02)
Divalent tin enolates, formed from stannous triflate and ketones, react with a second ketone under mild conditions to afford the corresponding cross-aldol products in good to excellent yields.In the case of the cross-coupling with aromatic ketone, enhance
