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33868-50-7

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33868-50-7 Usage

Chemical Properties

solid

Synthesis Reference(s)

Synthetic Communications, 18, p. 1167, 1988 DOI: 10.1080/00397918808060904Tetrahedron Letters, 18, p. 599, 1977

Check Digit Verification of cas no

The CAS Registry Mumber 33868-50-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,3,8,6 and 8 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 33868-50:
(7*3)+(6*3)+(5*8)+(4*6)+(3*8)+(2*5)+(1*0)=137
137 % 10 = 7
So 33868-50-7 is a valid CAS Registry Number.
InChI:InChI=1/C15H12O3/c16-14(12-7-3-1-4-8-12)11-18-15(17)13-9-5-2-6-10-13/h1-10H,11H2

33868-50-7Relevant articles and documents

Bioinspired Oxidative Cleavage of Aliphatic C–C Bonds Utilizing Aerial Oxygen by Nickel Acireductone Dioxygenase Mimics

Raje, Sakthi,Mani, Kalaikodikumaran,Kandasamy, Parameswaran,Butcher, Ray J.,Angamuthu, Raja

, p. 2164 - 2167 (2019)

Bioinspired oxidative cleavage of aliphatic C–C bonds of the acireductone model substrate 2-hydroxy-3-oxo-1,3-diphenylprop-1-en-1-olate, bound to two paramagnetic nickel(II) complexes that are mimics for the nickel containing acireductone dioxygenase, has been achieved utilizing aerial oxygen under ambient conditions.

N-Heterocyclic Carbene Catalyzed Ester Synthesis from Organic Halides through Incorporation of Oxygen Atoms from Air

Tan, Hui,Wang, Shen-An,Yan, Zixi,Liu, Jianzhong,Wei, Jialiang,Song, Song,Jiao, Ning

supporting information, p. 2140 - 2144 (2020/12/01)

Oxygenation reactions with molecular oxygen (O2) as the oxygen source provides a green and straightforward strategy for the construction of O-containing compounds. Demonstrated here is a novel N-heterocyclic carbene (NHC) catalyzed oxidative transformation of simple and readily available organic halides into valuable esters through the incorporation of O-atoms from O2. Mechanistic studies prove that the deoxy Breslow intermediate generated in situ is oxidized to a Breslow intermediate for further transformation by this oxidative protocol. This method broadens the field of NHC catalysis and promotes oxygenation reactions with O2.

Aerobic Photooxidative Synthesis of β-Alkoxy Monohydroperoxides Using an Organo Photoredox Catalyst Controlled by a Base

Asano, Yuya,Nagasawa, Yoshitomo,Yamaguchi, Eiji,Itoh, Akichika

supporting information, p. 409 - 412 (2018/02/21)

Transition-metal-free synthesis of β-alkoxy monohydroperoxides via aerobic photooxidation using an acridinium photocatalyst was developed. This method enables the synthesis of some novel hydroperoxides. The peroxide source is molecular oxygen, which is cost-effective and atomically efficient. Magnesium oxide plays an important role as a base in the catalytic system.

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