844867-44-3Relevant academic research and scientific papers
Stepwise hydrolysis of aluminum chloride iodide LAlClI (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) in the presence of N-heterocyclic carbene as hydrogen halide acceptor
Zhu, Hongping,Chai, Jianfang,He, Cheng,Bai, Guangcai,Roesky, Herbert W.,Jancik, Vojtech,Schmidt, Hans-Georg,Noltemeyer, Mathias
, p. 380 - 384 (2005)
The aluminum chloride iodide LAlClI (2, L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) has been synthesized to study the stepwise hydrolysis of this compound in the presence of 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene as hydrogen halide acceptor. The isolation and characterization of the aluminum chloride hydroxide [LAlCl(μ-OH)]2 (3) and the dihydroxide LAl(OH)2 (4) demonstrate the realization of a controlled hydrolysis.
