84543-52-2Relevant academic research and scientific papers
Copper-Catalyzed Oxidative Trifunctionalization of Olefins: An Access to Functionalized β-Keto Thiosulfones
Huang, Shuai,Thirupathi, Nuligonda,Tung, Chen-Ho,Xu, Zhenghu
, p. 9449 - 9455 (2018/08/01)
Aerobic oxidative trifunctionalization of olefins for the synthesis of functionalized β-keto thiosulfones has been described. The transformation proceeds through molecular oxygen activation under copper catalysis and forms the two new C-S bonds in a single operation using mild conditions. A novel Cu-catalyzed sulfonyl radical addition/oxidation/funtionalization relay mechanism was proposed for the discovered reaction.
On the Control of Sulphenylations at Carbon
Grossert, J. Stuart,Dubey, Pramod K.
, p. 1183 - 1184 (2007/10/02)
Controlled monosulphenylation at carbon adjacent to electron-withdrawing groups can be achieved by the controlled reduction of readily available bis-sulphenylated products.
