NOVEL TRANSITION METAL PHOSPHA-ALKYNE COMPLEXES: tBuCP ACTING AS A 6 ELECTRON DONOR LIGAND. SYNTHESIS, CRYSTAL AND MOLECULAR STRUCTURE OF tBuCP)W(CO)5>

Article abstract of DOI:10.1016/S0022-328X(00)83810-3

A single crystal X-ray diffraction study of tBuCP)W(CO)5> establishes that phospha-alkyne behaves as a 6e donor.Synthesis of the related <(η⁵-C5H5)2Mo2(CO)4(μ-^tBuCP)W(CO)5> complex is reported.