84695-12-5Relevant academic research and scientific papers
Carbamates: A Directing Group for Selective C-H Amidation and Alkylation under Cp*Co(III) Catalysis
Bera, Sourav Sekhar,Maji, Modhu Sudan
supporting information, p. 2615 - 2620 (2020/04/08)
The selective reactivity of carbamate and thiocarbamate toward alkylation and amidation is reported under stable, high-valent, cost-effective cobalt(III) catalysis. This method reveals the wide possibility of designing a different branch of synthetically
Base-Promoted Synthesis of O -Aryl/Alkyl N, N -Dimethylthiocarbamates Starting from Inexpensive and Environmentally Benign Disulfide
Dong, Zhi-Bing,Wang, Ming,Zhu, Hui,Liu, Xing,Chang, Cai-Zhu
, p. 5258 - 5262 (2017/10/06)
A series of O -aryl (alkyl) N, N -dimethylthiocarbamates were synthesized in good yields (70-77%) by reacting substituted phenols or alkyl alcohol with inexpensive, stable, and environmentally benign tetramethylthiuram disulfide (TMTD) in the presence of NaH. By avoiding use of the toxic and corrosive N, N -dialkylthiocarbamoyl chloride, the method provides a green and facile preparation for some important precursors of potentially biologically reactive compounds.
An improved synthesis and structural characterisation of 2-(4-acetylthiophenylethynyl)-4-nitro-5-phenylethynylaniline: The molecule showing high negative differential resistance (NDR)
Wang, Changsheng,Batsanov, Andrei S.,Bryce, Martin R.,Sage, Ian
, p. 2089 - 2095 (2007/10/03)
2-(4-Acetylthiophenylethynyl)-4-nitro-5-phenyl-ethynylaniline (11) has been synthesised by an improved route, which has many advantages over the literature procedure. A key intermediate is 2-ethynyl-4-nitro-5-phenylethynylaniline (6) which is obtained fro
Infrared Spectra and Transmission of Electronic Effects in Substituted Phenyl N,N-Dimethylcarbamates and S-Phenyl N,N-Dimethylthiocarbamates
Perjessy, Alexander,Jones, Ronald G.,McClair, Susan L.,Wilkins, Joyce M.
, p. 1266 - 1271 (2007/10/02)
Carbonyl stretching frequencies in CCl4 and CHCl3 and hydroxyl stretching frequency shifts of phenol as a proton donor in CCl4 were measured for series of substituted phenyl N,N-dimethylcarbamates (I) and S-phenyl N,N-dimethylthiocarbamates (II).The data
