84736-54-9

Basic information

• Product Name: 3-Pentanone, 2-(4-methoxyphenyl)-
• CAS NO: 84736-54-9
• Molecular Formula: C12H16O2
• Molecular Weight: 192.258
• Mol File: 84736-54-9.mol
• Article Data: 10

Chemical Properties

• CAS DataBase Reference: 3-Pentanone, 2-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Pentanone, 2-(4-methoxyphenyl)-(84736-54-9)
• EPA Substance Registry System: 3-Pentanone, 2-(4-methoxyphenyl)-(84736-54-9)

Safety Data

• Hazardous Substances Data: 84736-54-9(Hazardous Substances Data)

Upstream product

• 17403-82-6 3-(p-methoxyphenyl)-2-pentene 
• 857818-06-5 2-(4-methoxyphenyl)-2-methylbutyraldehyde 
• 53917-01-4 1-(4-methoxyphenyl)butan-2-one 
• 74-88-4 methyl iodide 
• 18649-43-9 4-methoxyphenyllead(IV) triacetate 
• 13654-48-3 4-(1-ethyl-1-propenyl)morpholine 
• 623-12-1 4-chloromethoxybenzene 
• 96-22-0 pentan-3-one 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 616-25-1 1-Penten-3-ol 
• 17510-47-3 3-trimethylsilyloxy-2-pentene 
• 39831-53-3 1-(but-2-en-1-yl)-4-methoxybenzene 
• 696-62-8 para-iodoanisole 
• 1373765-00-4 2,4-bis(4-methoxyphenyl)pentan-3-one 

Relevant articles and documents

Two efficient pathways for the synthesis of aryl ketones catalyzed by phosphorus-free palladium catalysts

Allylic alcohols, 1-buten-3-ol, 1-penten-3-ol and 1-octen-3-ol, reacted with aryl iodides (iodotoluene, 4-iodotoluene, 4-iodophenol and 4-iodanisole) under Heck reaction conditions to form corresponding saturated aryl ketones in one step. The same products were obtained in a two-step tandem reaction consisted of the Heck coupling of allylic alcohols with aryl iodides, followed by hydrogenation. Reactions were catalyzed by phosphorus-free palladium precursors modified with the menthol-substituted imidazolium chlorides. Formation of crystalline palladium nanoparticles, of the diameter up to 65 nm, in the reaction mixture was evidenced by TEM.

N-Heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed a-arylation of symmetric dialkyl ketones with aryl chlorides

N-Heterocyclic carbene-palladium(II)-1-methylimidazole [NHC-Pd(II)-Im] complex 1 showed efficient catalytic activity toward α-arylation of symmetric dialkyl ketones under mild conditions. It was found that the ratio of aryl chlorides and ketones drastical

N-heterocyclic carbene-palladium(II)-1-methylimidazole complex catalyzed α-arylation of ketones with aryl chlorides

An easily available NHC-Pd(II)-Im (NHC=N-heterocyclic carbene, Im=1-methylimidazole) complex was found to be an efficient catalyst for the α-arylation reaction between ketones and aryl chlorides. Under the optimal conditions, all reactions proceeded smoot