84755-34-0Relevant academic research and scientific papers
Ethyl Esters of Malonanilic Acids. Synthesis and Pyrolysis
Ukrainets, Igor V.,Bezugly, Peter A.,Treskach, Vladimir I.,Taran, Svetlana G.,Gorokhova, Olga V.
, p. 10331 - 10338 (2007/10/02)
The pyrolysis under 170-220 deg C or boiling in DMF of malonanilic acids ethyl esters (2) is accompanied by formation of malonic acids symmetric dianilides (7) with high yields.A possible mechanism for this transformation has been suggested.
Efficient Synthesis of Benzo-Substituted Macrocyclic Diamides
Ibrahim, Yehia A.,Elwahy, Ahmed H. M.
, p. 1684 - 1696 (2007/10/02)
A series of new 13-16-membered macrocyclic dibenzo- and tribenzodioxadiamides and trioxadiamides (macrooxacyclams) 3-9, 11-13 has been prepared.Good to excellent yields (32-87percent) were achieved in the macrocyclization step by reacting the dipotassium
ACYLATION OF ORTHO(PARA)-SUBSTITUTED AROMATIC AMINES BY MALONIC ACID DERIVATIVES
Bezuglyi, P. A.,Treskach, V. I.,Ukrainets, I. V.,Grinenko, V. V.,Bevz, N. Yu.
, p. 1233 - 1236 (2007/10/02)
The reaction of diethyl malonate with primary ortho(para)-substituted arylamines leads to the formation of ethyl malonanilates or symmetrical malonanilides, depending on the temperature and on the nucleophilic characteristics of the amines.
