848900-41-4Relevant articles and documents
Total synthesis of fuzinoside
He, Ping,Li, Xiao-Huan,Chen, Qiao-Hong,Yang, Jing-Song,Wang, Feng-Peng
, p. 4022 - 4030 (2014/06/09)
The first total syntheses of fuzinoside (1b) were achieved from d-galactose through two strategies (BCA and ABC) in 11 (total yield: 5.0%) and 15 (total yield: 3.7%) steps, respectively. Comparison of NMR data of synthetic compound 1b and those of the fuzinoside isolated from the lateral roots of Aconitum carmicaelii suggests that the structure reported in the literature1,2 might not be accurate. The synthetic fuzinoside (1b) exhibited moderate cardiac activity in the isolated bullfrog heart assay.
2,3-Anhydrosugars in glycoside bond synthesis. Application to α-D-galactofuranosides
Bai, Yu,Lowary, Todd L.
, p. 9658 - 9671 (2007/10/03)
We report here the use of 2,3-anhydro-D-gulofuranosyl thioglycosides and glycosyl sulfoxides in the synthesis of α-D-galactofuranosidic bonds, which are present in a range of bacterial and fungal glycoconjugates. This two-step method involves a stereosele