84906-66-1Relevant academic research and scientific papers
A FACILE SYNTHESIS OF PRIMARY AMINES FROM CARBOXYLIC ACIDS BY THE CURTIUS REARRANGEMENT
Capson, Todd L.,Poulter, C. Dale
, p. 3515 - 3518 (1984)
2-Trimethylsilylethanol was used to trap isocyanates produced by the Curtius rearrangement of acyl azides and the resulting trimethylsilylethyl carbamates were readily cleaved with tetra-n-butylammonium fluoride to liberate the primary amines.
