Tetrahedron Letters p. 3515 - 3518 (1984)
Update date:2022-08-04
Topics:
Capson, Todd L.
Poulter, C. Dale
2-Trimethylsilylethanol was used to trap isocyanates produced by the Curtius rearrangement of acyl azides and the resulting trimethylsilylethyl carbamates were readily cleaved with tetra-n-butylammonium fluoride to liberate the primary amines.
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