A FACILE SYNTHESIS OF PRIMARY AMINES FROM CARBOXYLIC ACIDS BY THE CURTIUS REARRANGEMENT

DOI: 10.1016/S0040-4039(01)91063-9

Source and publish data:

Tetrahedron Letters p. 3515 - 3518 (1984)

Update date:2022-08-04

Topics:

Authors:

Capson, Todd L.

Poulter, C. Dale

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Article abstract of DOI:10.1016/S0040-4039(01)91063-9

2-Trimethylsilylethanol was used to trap isocyanates produced by the Curtius rearrangement of acyl azides and the resulting trimethylsilylethyl carbamates were readily cleaved with tetra-n-butylammonium fluoride to liberate the primary amines.

Full text of DOI:10.1016/S0040-4039(01)91063-9

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Product name:Carbamic acid, cyclohexyl-, 2-(trimethylsilyl)ethyl ester

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