849406-74-2Relevant academic research and scientific papers
Studies on the reactivity of the four-membered base-stabilized iminoalane [(Me3N)HAlNDipp]2 with elemental iodine
Bauer, Tillmann,Schulz, Stephan,Nieger, Martin
, p. 1807 - 1810 (2004)
The base-stabilized iminoalane [(Me3N)HAlNDipp]2 (Dipp = 2,6-iPr2C6H3) reacts with iodine under substitution of the hydridic H atom at the Al center and formation of HI, which subsequently protonates the Lewis basic imin nitrogen. A mixture of [DippN{AlI2(NMe3)}2] (1), [DippN(H)AlI 2(NMe3)] (2), [{DippN(H)}2AlI(NMe3)] (3) and DippNH2 is formed. 1-3 were identified by spectroscopic methods (1H, 13C, IR, and mass spectroscopy), 1 and 2 also by single crystal X-ray diffraction.
