84952-10-3Relevant academic research and scientific papers
Dinuclear metallocene compound, catalyst composition and method for preparing olein polymer using the same
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Paragraph 0149-0153, (2021/02/09)
The present invention relates to a dinuclear metallocene compound, a catalyst compound, and a method for manufacturing an olefin polymer using the same. An embodiment of the present invention provides the dinuclear metallocene compound represented by chem
Photochemical site-selective synthesis of [70]methanofullerenes
Vidal, Sara,Izquierdo, Marta,Law, Wai Kit,Jiang, Kui,Filippone, Salvatore,Perles, Josefina,Yan, He,Martín, Nazario
supporting information, p. 12733 - 12736 (2016/11/02)
Methanofullerenes such as the well-known [70]PCBM are commonly synthesized under harsh conditions to obtain the product as a mixture of site-isomers (namely α, β and minor γ) due to the D5h symmetry of the C70 cage. We report the fir
Reaction of diazocompounds with C70: unprecedented synthesis and characterization of isomeric [5,6]-fulleroids
Vidal, Sara,Izquierdo, Marta,Filippone, Salvatore,Brunetti, Fulvio G.,Martín, Nazario
supporting information, p. 16774 - 16777 (2015/11/27)
The synthesis of a variety of PCBM-type [5,6]-fulleroids and their further highly selective photoisomerization to the respective [6,6]-methanofullerenes is presented. Interestingly, the chemical reactivity of [5,6]-fulleroids reveals the same trend (a > b
Oxalyl chloride as carbonyl synthon in Pd-catalyzed carbonylations of triarylbismuth and triarylindium organometallic nucleophiles
Rao, Maddali L. N.,Venkatesh, Varadhachari,Dasgupta, Priyabrata
experimental part, p. 4975 - 4980 (2011/01/12)
Oxalyl chloride has been demonstrated to function as C1 carbonyl synthon in the carbonylations of triarylbismuth and triarylindium nucleophiles under palladium-catalyzed conditions. All the three aryl groups from both bismuth and indium reagents participated in carbonylative couplings to afford the corresponding functionalized ketones in high yields. This study also disclosed a novel utilization of oxalyl chloride as facile alternative source of CO for carbonylations under palladium catalysis.
