84998-58-3

Basic information

• Product Name: Phosphinous acid, bis(1-methylethyl)-, 2-bromophenyl ester
• CAS NO: 84998-58-3
• Molecular Formula: C12H18BrOP
• Molecular Weight: 289.152
• Mol File: 84998-58-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Phosphinous acid, bis(1-methylethyl)-, 2-bromophenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphinous acid, bis(1-methylethyl)-, 2-bromophenyl ester(84998-58-3)
• EPA Substance Registry System: Phosphinous acid, bis(1-methylethyl)-, 2-bromophenyl ester(84998-58-3)

Safety Data

• Hazardous Substances Data: 84998-58-3(Hazardous Substances Data)

Upstream product

• 95-56-7 2-hydroxybromobenzene 
• 72740-05-7 N-dimethylaminodiisopropylphosphine 
• 40244-90-4 Chlorodiisopropylphosphane 

Downstream Products

• 1035697-06-3 trans-(κ2-P,C-C6H4OP(iPr)2)NiBr(P(iPr)2OC6H4Br) 
• 952685-27-7 cis-[PtCl₂((2-bromophenoxy)diisopropylphosphane)2] 
• 1020188-57-1 (1Z,5Z-cyclooctadiene)Rh(Cl)(2-Br-phenyl-O-(diisopropylphosphinite)) 
• 6372-43-6 diisopropylphenylphosphane 
• 63059-00-7 butyldiisopropylphosphine 
• 36601-47-5 2-bromophenyl trimethylsilyl ether 

Relevant articles and documents

Some phosphinite complexes of Rh and Ir, their intramolecular reactivity and DFT calculations about their application in biphenyl metathesis

Biphen(OPR2) (with R: Ph, iPr, Cy) is reacted with [Rh(COE)2Cl]2. The corresponding μ-chloro-bridged dimers are received. An X-ray analysis of [Biphen(OPCy2)RhCl]2 is included. This compound shows a d

o-PHOSPHINOPHENOLE DURCH 1,3-CARBANIONISCHE UMLAGERUNGEN o-METALLIERTER AROXYPHOSPHINE

Phosphinous acid o-bromoaryl esters or phosphorous acid o-haloaryl ester diamides react with sodium under mild conditions to give the corresponding sodium aryls which undergo rapid 1,3-carbanionic rearrangements to give o-phosphinophenolates.These may be worked up to the free phenoles or silylated by treatment with Me3SiCl.