85013-34-9Relevant articles and documents
Mechanistic Investigation of Oxygen Rebound in a Mononuclear Nonheme Iron Complex
Pangia, Thomas M.,Yadav, Vishal,Gérard, Emilie F.,Lin, Yen-Ting,De Visser, Sam P.,Jameson, Guy N. L.,Goldberg, David P.
, p. 9557 - 9561 (2019)
An iron(III) methoxide complex reacts with para-substituted triarylmethyl radicals to give iron(II) and methoxyether products. Second-order rate constants for the radical derivatives were obtained. Hammett and Marcus plots suggest the radical transfer rea
Photolysis of Triarylacetonitriles. A Novel Photochemical Generation of Phenyl(cyano)carbene
Shi, Min,Okamoto, Yoshiki,Takamuku, Setsuo
, p. 1044 - 1054 (2007/10/02)
Upon UV irradiation in methanol, triarylacetonitrile underwent a novel α,α-elimination of two aryl groups to give biaryl and α-methoxyarylacetonitrile.However, when a methoxy group was introduced into the phenyl group, another photochemical process which gave the corresponding triarylmethane and methoxytriarylmethane as major products took place simultaneously.