850331-71-4

Basic information

• Product Name: Benzenesulfonamide, N-(2-iodophenyl)-4-methyl-N-2-propenyl-
• CAS NO: 850331-71-4
• Molecular Formula: C16H16INO2S
• Molecular Weight: 413.279
• Mol File: 850331-71-4.mol

Chemical Properties

• CAS DataBase Reference: Benzenesulfonamide, N-(2-iodophenyl)-4-methyl-N-2-propenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenesulfonamide, N-(2-iodophenyl)-4-methyl-N-2-propenyl-(850331-71-4)
• EPA Substance Registry System: Benzenesulfonamide, N-(2-iodophenyl)-4-methyl-N-2-propenyl-(850331-71-4)

Safety Data

• Hazardous Substances Data: 850331-71-4(Hazardous Substances Data)

Upstream product

• 591-87-7 Allyl acetate 
• 61613-20-5 N-tosyl-2-iodoaniline 
• 615-43-0 2-iodophenylamine 
• 106-95-6 allyl bromide 
• 107-05-1 3-chloroprop-1-ene 
• 98-59-9 p-toluenesulfonyl chloride 
• 68-34-8 phenyl toluenesulfonamide 

Downstream Products

• 36797-43-0 3-methyl-N-(p-toluenesulfonyl)indole 
• 1403266-87-4 3-methyl-1-tosylindoline 

Relevant articles and documents

Palladium-Catalyzed Chemoselective Oxidative Addition of Allyloxy-Tethered Aryl Iodides: Synthesis of Medium-Sized Rings and Mechanistic Studies

This Letter describes a Pd-catalyzed Tsuji-Trost-type/Heck reaction with allyloxy-tethered aryl iodides and aziridines. The strategy provides efficient access to benzannulated medium-sized rings via intermolecular cyclization. The substrate aryl iodide ha

Formal Bromine Atom Transfer Radical Addition of Nonactivated Bromoalkanes Using Photoredox Gold Catalysis

Organic transformations mediated by photoredox catalysis have been at the forefront of reaction discovery. Recently, it has been demonstrated that binuclear Au(I) bisphosphine complexes, such as [Au2(μ-dppm)2]X2, are capable of mediating electron transfer to nonactivated bromoalkanes for the generation of a variety of alkyl radicals. The transfer reactions of bromine, derived from nonactivated bromoalkanes, are largely unknown. Therefore, we propose that unique metal-based mechanistic pathways are at play, as this binuclear gold catalyst has been known to produce Au(III) Lewis acid intermediates. The scope and proposed mechanistic overview for the formal bromine atom transfer reaction of nonactivated bromoalkanes mediated by photoredox Au(I) catalysis is presented. The methodology presented afforded good yields and a broad scope which include examples using bromoalkanes and iodoarenes.

The development of domino reactions incorporating the heck reaction: The formation of N-heterocycles

The methodological development of a series of domino or cascade reactions affording a series of N-heterocycles is described. The rapid formation of these ring systems is in each case associated with the incorporation of a Heck reaction at either an early