85048-19-7

Upstream product

• 50-00-0 formaldehyd 
• 13294-73-0 1-tert-butyl-4-methylenecyclohexane 
• 75-24-1 trimethylaluminum 
• 28835-96-3 (4-tert-butylcyclohexylidene)acetic acid 
• 54280-91-0 1-<(ethoxycarbonyl)methyl>-4-tert-butylcyclohexanol 
• 1240401-57-3 2-(4-tert-butylcyclohexylidene)ethyl picolinate 
• 557-20-0 diethylzinc 
• 920-39-8 isopropylmagnesium bromide 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 129518-99-6 ethyl (4-tert-butylcyclohexylidene)acetate 
• 13278-24-5 acide hydroxy-1 tertiobutyl-4 cyclohexane-acetique 
• 88166-26-1 methyl 4-tert-butylcyclohexylideneacetate 

Downstream Products

• 109787-60-2 1-<<2-<2-(4-(2,2-dimethylethyl)cyclohexylidene)ethoxy>-3-methyl-2-butenyl>sulfonyl>-4-methylbenzene 
• 56300-88-0 2-(4-tert-butylcyclohexylidene)acetaldehyde 
• 75646-57-0 2-(4'-t-butylcyclohexylidene)ethyl bromide 
• 77927-90-3 [2-(4-tert-Butyl-cyclohexylidene)-ethoxy]-acetic acid 
• 503003-89-2 4-tert-butyl-1-vinyl-cyclohexanethiol 
• 503003-71-2 C₁₂H₂₁NOS 
• 503003-69-8 C₁₂H₂₁NOS 
• 503003-85-8 dithiocarbonic acid S-(4-tert-butyl-1-vinyl-cyclohexyl) ester S-methyl ester 
• 105962-03-6 (1E)-2-<4'-(tert-butyl)cyclohex-1'-enyl>-N,N-dimethylethen-1-ylamine 
• 40585-97-5 trans-4-t-butylcyclohexane-1-carbaldehyde 
• 40585-98-6 cis-4-t-butylcyclohexane-1-carbaldehyde 
• 75646-58-1 2-(4'-t-butyl-1'-vinylcyclohex-1'-yl)-2-(pyrrolidin-1''-yl)acetonitrile 
• 77928-00-8 (4-tert-Butyl-1-vinyl-cyclohexyl)-hydroxy-acetic acid 
• 1240401-57-3 2-(4-tert-butylcyclohexylidene)ethyl picolinate 

Relevant academic research and scientific papers

Synthesis and Biological Activity of New 4-tert-Butylcyclohexanone Derivatives

In the synthesis performed in this study, derivatives of 4-tert-butylcyclohexanone 1 were obtained using typical reactions of organic synthesis. The bioactivity of the selected compounds was evaluated. 1-(Bromomethyl)-8-tert-butyl-2-oxaspiro[4.5]decan-3-o

Construction of a quaternary carbon at the carbonyl carbon of the cyclohexane ring

High SN2′ selectivity in the allylic substitution of cyclohexylidene ethyl picolinates with copper reagents prepared from RMgBr and CuBr·Me2S was realized by addition of ZnX2 (X = I, Br, Cl). Furthermore, ZnX2 accelerated the reaction with the bulky iPr reagent. The Royal Society of Chemistry 2010.

Thioepoxide formation by ring closure of allylthiyl radicals - A novel rearrangement of allylic thionitrites

Tertiary allylic thionitrites undergo thermal rearrangement to α,β-episulfide nitroso dimers via ring closure of allylthiyl radicals.

98. A Regioselective Cyclohexannulation Procedure via Dienamine Cycloaddition. Synthesis of Functionalised Decalins

A regioselective cyclohexannulation procedure, whose key step involves the cycloaddition of dienamines 12-24 with methyl acrylate, allows the conversion of cycloalkanones 1-11 to bicyclic dienoates 25-37.The chemistry of 26 is briefly examined and, in the context of organoleptic studies concerning functionalised 5,5,9-trimethyldecalins, the transformation of 37 to ketones 44 and 46 as well as to acetates 53-56 is described.

Reactions of the Formaldehyde-Trimethylaluminum Complex with Alkenes

Reaction of CH2O*Me3Al with electron-rich alkenes gives a zwitterion that reacts further to give homoallylic alcohols (ene adducts), allylic alcohols, and the product of cis addition of a hydroxymethyl and a methyl group to the double bond.The stereochemistry and effect of alkene structure on the nature of the reaction are examined.

Studies on Intramolecular Alkylation. XII. Stereochemical Aspects of the Preparation of β,γ-Unsaturated Aldehydes from the -Sigmatropic Rearrangement of Ammonium Ylides

The -sigmatropic rearrangement of a series of acetonitrile-derived allylic ammonium ylides +(C4H8)-CHCN; R = 4'-t-butylcyclohexylidenemethyl (3), 4'-t-butylcyclohex-1-enyl (10), 5'-t-butyl-2'-methylcyclohex-1-enyl (14), 4'