850694-63-2Relevant academic research and scientific papers
Visible light-induced C-C bond cleavage in a multicomponent reaction cascade allowing acylations of sulfoximines with ketones
Bolm, Carsten,Ma, Ding,Shi, Peng,Tu, Yongliang,Wang, Chenyang,Zhang, Duo
supporting information, p. 8096 - 8101 (2021/10/04)
Visible light induces C-C-bond cleavage reactions of ketones, which can be utilized forN-acylations of sulfoximines. No (photo)catalyst is required, and the reactions occur at ambient temperature in air. The substrate scope is broad for both ketones and sulfoximines. For convertingNH-sulfoximines, the presence of NBS is essential.
Copper-catalyzed oxidative decarboxylative coupling of α-keto acids and sulfoximines
Pimpasri, Chaleena,Sumunnee, Ladawan,Yotphan, Sirilata
, p. 4320 - 4327 (2017/07/10)
A copper-catalyzed oxidative decarboxylative coupling of α-keto acids with NH-sulfoximines has been developed. With CuBr as the catalyst and K2S2O8 as the oxidant, this reaction enables the formation of a C-N bond and gives N-aroylsulfoximine products in moderate to excellent yields. The reaction mechanism is likely to involve the generation of a reactive aroyl radical intermediate.
Palladium-catalyzed α-arylation of sulfoximines
Cho, Gae Young,Bolm, Carsten
, p. 1351 - 1354 (2007/10/03)
(Chemical Equation Presented). Palladium-catalyzed α-arylation of N-benzoyl sulfoximine ethyl ester with various aryl bromides leads to α-arylated products that can easily be hydrolyzed, giving the corresponding N-protected benzyl phenyl sulfoximines. In
