851591-22-5Relevant academic research and scientific papers
Iron-catalyzed aryl-aryl cross-couplings with magnesium-derived copper reagents
Sapountzis, Ioannis,Lin, Wenwei,Kofink, Christiane C.,Despotopoulou, Christina,Knochel, Paul
, p. 1654 - 1657 (2005)
(Chemical Equation Presented) Well-matched couples: Functionalized aryl and heteroaryl copper species obtained from the corresponding magnesium derivatives undergo Fe-catalyzed cross-coupling reactions with aryl iodides that bear keto, ester, triflate, or nitrile groups (see scheme).
Cobalt(II)-catalyzed cross-coupling between polyfunctional arylcopper reagents and aryl fluorides or tosylates
Korn, Tobias J.,Schade, Matthias A.,Wirth, Stefan,Knochel, Paul
, p. 725 - 728 (2007/10/03)
Organocopper compounds prepared by the transmetalation of functionalized arylmagnesium halides with CuCN-2LiCI undergo smooth cross-coupling reactions with aryl fluorides and tosylates bearing a carbonyl function in the ortho position in the presence of C
