851763-62-7Relevant academic research and scientific papers
Hydrozirconation of acetylenic chalcogenides. Synthesis and reactions of zirconated vinyl chalcogenide intermediates
Dabdoub, Miguel J.,Begnini, Mauro L.,Guerrero Jr., Palimecio G.
, p. 2371 - 2400 (1998)
Acetylenic tellurides react with Cp2Zr(H)Cl in THF at room temperature to give the α-zirconated vinyl telluride intermediates 39, which react with a wide range of electrophiles to give several types of trisubstituted olefins, such as α-halo vin
Stereoselective synthesis of 1,3-enynyltellurides via palladium catalysed cross-coupling reaction of (E)-α-iodovinyltellurides
Cai, Mingzhong,Chan, Junmin
, p. 840 - 842 (2007/10/03)
(E)-α-Iodovinyltellurides undergo a direct coupling reaction with terminal alkynes in the presence of [Pd(PPh3)4] and CuI catalysts in pyrrolidine at room temperature to give 1,3-enynyltellurides in good yields.
