Hydrozirconation of acetylenic chalcogenides. Synthesis and reactions of zirconated vinyl chalcogenide intermediates

DOI: 10.1016/S0040-4020(98)00014-3

Source and publish data:

Tetrahedron p. 2371 - 2400 (1998)

Update date:2022-07-30

Topics:

Authors:

Dabdoub, Miguel J.

Begnini, Mauro L.

Guerrero Jr., Palimecio G.

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Article abstract of DOI:10.1016/S0040-4020(98)00014-3

Acetylenic tellurides react with Cp₂Zr(H)Cl in THF at room temperature to give the α-zirconated vinyl telluride intermediates 39, which react with a wide range of electrophiles to give several types of trisubstituted olefins, such as α-halo vin

Full text of DOI:10.1016/S0040-4020(98)00014-3

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