852292-29-6Relevant academic research and scientific papers
Palladium-Catalyzed Regioselective Synthesis of 1-Hydroxycarbazoles Under Aerobic Conditions
Youn, So Won,Kim, Young Ho,Jo, Yoon Hyung
supporting information, p. 462 - 468 (2019/01/04)
A palladium-catalyzed aerobic C?H amidation of N-Ts-2-amino-3′-hydroxylbiaryls has been developed to afford a diverse range of 1-hydroxycarbazoles with high regioselectivity and efficiency. This protocol benefits from operational simplicity, robustness, a
Synthesis of 2-BMIDA 6,5-bicyclic heterocycles by Cu(i)/Pd(0)/Cu(II) cascade catalysis of 2-iodoaniline/phenols
Seath, Ciaran P.,Wilson, Kirsty L.,Campbell, Angus,Mowat, Jenna M.,Watson, Allan J.B.
supporting information, p. 8703 - 8706 (2016/07/15)
A one-pot cascade reaction for the synthesis of 2-BMIDA 6,5-bicyclic heterocycles has been developed using Cu(i)/Pd(0)/Cu(ii) catalysis. 2-Iodoanilines and phenols undergo a Cu(i)/Pd(0)-catalyzed Sonogashira reaction with ethynyl BMIDA followed by in situ Cu(ii)-catalyzed 5-endo-dig cyclization to generate heterocyclic scaffolds with a BMIDA functional group in the 2-position. The method provides efficient access to borylated indoles, benzofurans, and aza-derivatives, which can be difficult to access through alternative methods.
Palladium-catalyzed intramolecular reductive cross-coupling of Csp 2-Csp3 bond formation
Liu, Hui,Wei, Jianpeng,Qiao, Zongjun,Fu, Yana,Jiang, Xuefeng
supporting information, p. 8308 - 8313 (2014/07/08)
A Pd-catalyzed efficient reductive cross-coupling reaction without metallic reductant to construct a Csp2-Csp3 bond has been reported. A PdIV complex was proposed to be a key intermediate, which subsequently went through d
Efficient access to 1,4-benzothiazine: Palladium-catalyzed double C-S bond formation using Na2S2O3 as sulfurating reagent
Qiao, Zongjun,Liu, Hui,Xiao, Xiao,Fu, Yana,Wei, Jianpeng,Li, Yuxue,Jiang, Xuefeng
supporting information, p. 2594 - 2597 (2013/07/19)
A novel Pd-catalyzed double C-S bond formation coupling reaction has been developed. This protocol, in which Na2S2O3 was used as sulfurating reagent in metal-catalyzed reactions, provides an efficient method for the synthe
A new preparative route to substituted carbazoles by benzannulation
Serra, Stefano,Fuganti, Claudio
, p. 809 - 812 (2007/10/03)
A new regioselective pathway to substituted carbazole derivatives is described here. According to this procedure substituted 2-alkoxycarbonyl-4- acetoxy-9-(p-toluenesulfonyl) carbazoles are obtained by treatment of substituted 6-[2-(p-toluenesulfonyl-amin
