85292-69-9

Upstream product

• 1564-64-3 9-Bromoanthracene 
• 98-95-3 nitrobenzene 
• 120-12-7 anthracene 
• 119-66-4 2-nitrobenzenediazonium chloride 
• 100622-34-2 anthracene-9-boronic acid 
• 88-73-3 2-Chloronitrobenzene 
• 5570-19-4 2-nitrophenylboronic acid 
• 577-19-5 2-nitrophenyl bromide 
• 86-74-8 9H-carbazole 

Downstream Products

• 1252763-38-4 2-(anthracen-9-yl)aniline 
• 1060-61-3 9,10-bis-(2-nitro-phenyl)-anthracene 

Relevant academic research and scientific papers

An active catalytic system for Suzuki-Miyaura cross-coupling reactions using low levels of palladium loading

An easily available Pd(OAc)2/(2-(anthracen-9-yl)-1H-inden-3-yl) dicyclohexylphosphine/toluene/iPrOH/water catalytic system was developed, which shows high catalytic activity in the Suzuki-Miyaura cross-coupling reactions of a diverse array of aryl and heteroaryl chlorides with Pd loadings down to 0.01 mol%.

Iptycenes with an acridinone motif developed through [4+2] cycloaddition of tethered naphthalene and iminoquinone: Via a radical reaction

A new class of iptycenes was developed by combining 2-(naphthalen-1-yl)anilines and p-benzoquinones through copper(ii)-mediated radical cyclisation. This unusual cyclisation reaction resulted in the robust and efficient syntheses of iptycenes with an acridinone motif. These iptycenes can be further transformed into planar acridinone heterocyclics through the Diels-Alder reaction.

NOVEL COMPOUNDS, ORGANIC LIGHT EMITTING DEVICE DISPLAY AND ORGANIC SOLAR BATTERY USING THE SAME

The present invention refers to a fullerene derivative is denoted by chemical formula 1 a, including organic light emitting diode and same relates to organic solar cells. In said formula 1, R 1 to R 6, Ar 1, A, X and n as defined in the application equal the specification.

A thiourea-oxazoline library with axial chirality: Ligand synthesis and studies of the palladium-catalyzed enantioselective bis(methoxycarbonylation) of terminal olefins

We report herein the synthesis of novel chiral S,N-heterobidentate thiourea-oxazoline ligands and their application to palladium-catalyzed enantioselective bis(methoxycarbonylation)s of terminal olefins under mild conditions. Copper salts were found to play multiple roles in this reaction. Substituted 2- phenylsuccinates were obtained in >90% yield and up to 84% ee under optimized conditions.

Reaction of Carbazolylpotassium with 9-Bromoanthracene and Nitrobenzene

The formation of 9-(9-anthryl)carbazole (5) and 9-(2-nitrophenyl)anthracene (6) from 9-bromoanthracene (4), carbazole and nitrobenzene in the presence of potassium carbonate and catalytic amounts of copper is explained with the assumption of a trans-metallation equilibrium between carbazolylpotassium and nitrobenzene.