853200-65-4Relevant academic research and scientific papers
Synthesis of 3,3-dimethoxy-2-aryl-2,3-dihydro-1-oxa-cyclopenta[l] phenanthren-2-ols and their conversion to 2(3H)- and 3(2H)-furanones
Jacob, Ambily M.,Thumpakkara, Roshini K.,Prathapan, Sreedharan,Jose, Binoy
, p. 4601 - 4607 (2005)
A number of new 3,3-dimethoxy-2-aryl-2,3-dihydro-1-oxacyclopenta[l] phenanthren-2-ols were synthesized by the base-catalyzed reaction between phenanthrenequinone and 4-substituted acetophenones in methanol. These furanols are unstable and are easily converted to stable 3-methoxy-3-aryl-3H-1- oxacyclopenta[l]phenathren-2-ones in excellent yields. The furanols are converted to 2-aryl-1-oxacyclopenta[l]phenanthren-3-ones on treatment with acids. Plausible mechanisms for some of these new transformations are proposed.
