85370-73-6Relevant academic research and scientific papers
SILICON IN BENZAMIDE DIRECTED ORTHO METALATION REACTIONS. CARBO- AND BROMO-DESILYLATIONS AND SYNTHESIS OF NATURALLY-OCCURING ANTHRAQUINONES
Mills, R.J.,Snieckus, V.
, p. 483 - 486 (1984)
Silylated benzamides 2, avaible by directed ortho metalation, undergo fluorideinduced carbodesilylation and ipso bromodesilylation to give usefully-substituted aromatics 3 and 4; these reactions are utilized in a short and efficient synthesis of erythrola
