SILICON IN BENZAMIDE DIRECTED ORTHO METALATION REACTIONS. CARBO- AND BROMO-DESILYLATIONS AND SYNTHESIS OF NATURALLY-OCCURING ANTHRAQUINONES

DOI: 10.1016/S0040-4039(00)99917-9

Source and publish data:

Tetrahedron Letters p. 483 - 486 (1984)

Update date:2022-08-04

Topics:

Authors:

Mills, R.J.

Snieckus, V.

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Article abstract of DOI:10.1016/S0040-4039(00)99917-9

Silylated benzamides 2, avaible by directed ortho metalation, undergo fluorideinduced carbodesilylation and ipso bromodesilylation to give usefully-substituted aromatics 3 and 4; these reactions are utilized in a short and efficient synthesis of erythrola

Full text of DOI:10.1016/S0040-4039(00)99917-9

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