854139-13-2Relevant academic research and scientific papers
A method for synthesis of bicyclo[3.3.0]oct-1-en-3-ones from cyclobutanones with one-carbon ring expansion and its application to a formal synthesis of racemic 1-desoxyhypnophilin
Kashima, Hiroaki,Kawashima, Tadashi,Wakasugi, Daisuke,Satoh, Tsuyoshi
, p. 3953 - 3963 (2007/10/03)
A method for synthesis of 2-cyanobicyclo[3.3.0]oct-1-en-3-ones and 2-substituted bicyclo[3.3.0]oct-1-en-3-ones was developed by assembly of three components, cyclobutanones, chloromethyl p-tolyl sulfoxide, and nitriles, with one-carbon ring expansion of t
A novel synthesis of bicyclo[3.3.0]oct-1-en-3-ones from cyclobutanones through [chloro(p-tolylsulfinyl)methylidene]cyclobutanes with ring expansion
Kawashima, Tadashi,Kashima, Hiroaki,Wakasugi, Daisuke,Satoh, Tsuyoshi
, p. 3767 - 3770 (2007/10/03)
Treatment of [chloro(p-tolylsulfinyl)methylidene]cyclobutanes, which were synthesized from cyclobutanones and chloromethyl p-tolyl sulfoxide in three steps in high overall yields, with excess cyanomethyllithium gave enaminonitriles in high yields. Heating
