854139-16-5

Basic information

• Product Name: {1-[chloro(p-tolylsulfinyl)methyl]cyclobutyl}acetonitrile
• Synonyms: {1-[chloro(p-tolylsulfinyl)methyl]cyclobutyl}acetonitrile
• CAS NO: 854139-16-5
• Molecular Weight: 281.806
• Mol File: 854139-16-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: {1-[chloro(p-tolylsulfinyl)methyl]cyclobutyl}acetonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: {1-[chloro(p-tolylsulfinyl)methyl]cyclobutyl}acetonitrile(854139-16-5)
• EPA Substance Registry System: {1-[chloro(p-tolylsulfinyl)methyl]cyclobutyl}acetonitrile(854139-16-5)

Safety Data

• Hazardous Substances Data: 854139-16-5(Hazardous Substances Data)

Upstream product

• 99749-00-5 lithioacetonitrile 
• 854139-13-2 1-[chloro(p-tolylsulfinyl)methylidene]cyclobutane 
• 24824-93-9 chloromethyl p-tolyl sulfoxide 
• 938436-26-1 acetic acid 1-[chloro-(toluene-4-sulfinyl)-methyl]-cyclobutyl ester 
• 75-05-8 acetonitrile 

Downstream Products

• 854139-25-6 6-amino-7-(4-methoxyphenyl)spiro[3.4]octa-5,7-diene-5-carbonitrile 
• 854139-28-9 6-amino-7-trityl-spiro[3.4]octa-5,7-diene-5-carbonitrile 
• 854139-17-6 6-amino-7-phenylspiro[3.4]octa-5,7-diene-5-carbonitrile 

Relevant articles and documents

A method for synthesis of bicyclo[3.3.0]oct-1-en-3-ones from cyclobutanones with one-carbon ring expansion and its application to a formal synthesis of racemic 1-desoxyhypnophilin

A method for synthesis of 2-cyanobicyclo[3.3.0]oct-1-en-3-ones and 2-substituted bicyclo[3.3.0]oct-1-en-3-ones was developed by assembly of three components, cyclobutanones, chloromethyl p-tolyl sulfoxide, and nitriles, with one-carbon ring expansion of t