85428-13-3

Upstream product

• 102877-95-2 2,6-dimethyl-1-cyclohexenecarboxaldehyde 
• 85428-12-2 (2,6-dimethylcyclohex-1-enyl)methanol 
• 78-39-7 Triethyl orthoacetate 

Downstream Products

• 90461-17-9 1-((1R,3R)-1,3-Dimethyl-2-methylene-cyclohexyl)-propan-2-one 
• 85428-20-2 1-((1R,3S)-1,3-Dimethyl-2-methylene-cyclohexyl)-propan-2-one 
• 85428-14-4 4-((1R,3S)-1,3-Dimethyl-2-methylene-cyclohexyl)-3-oxo-butyric acid methyl ester 
• 85428-15-5 2-Diazo-4-((1R,3S)-1,3-dimethyl-2-methylene-cyclohexyl)-3-oxo-butyric acid methyl ester 
• 85428-21-3 C₂₁H₂₈N₂O₄S 

Relevant academic research and scientific papers

STEREOSPECIFIC TOTAL SYNTHESIS OF CYCLOEUDESMOL

A sterospecific sequence from the allylic alcohol 3 to the new antibiotic, cycloeudesmol 2, in 9 steps (21.7percent overall yield) is described.The key stereospecific construction of the bicyclo hexane system was conveniently achieved by an olefin

Total Synthesis of (+/-)-Cycloeudesmol and (+/-)- Epicycloeudesmol

The first total synthesis of both (+/-)-cycloeudesmol (3) and (+/-)-epicycloeudesmol (4) is described.The key stereospecific construction of the bicyclohexane system was conveniently achieved by an olefin-ketocarbene cyclization reaction.