85428-20-2Relevant articles and documents
Total Synthesis of (+/-)-Cycloeudesmol and (+/-)- Epicycloeudesmol
Chen, Edward Y.
, p. 3245 - 3250 (2007/10/02)
The first total synthesis of both (+/-)-cycloeudesmol (3) and (+/-)-epicycloeudesmol (4) is described.The key stereospecific construction of the bicyclohexane system was conveniently achieved by an olefin-ketocarbene cyclization reaction.
STEREOSPECIFIC TOTAL SYNTHESIS OF CYCLOEUDESMOL
Chen, Edward Y.
, p. 4769 - 4772 (2007/10/02)
A sterospecific sequence from the allylic alcohol 3 to the new antibiotic, cycloeudesmol 2, in 9 steps (21.7percent overall yield) is described.The key stereospecific construction of the bicyclo hexane system was conveniently achieved by an olefin