85436-56-2Relevant academic research and scientific papers
Oligophosphan-Liganden XXXII. Katalytische Dimerisierung von 1-Alkinen zu linearen 1-En-3-inen an cis-Arylhydridoruthenium(II)Chelatkomplexen. Molekuelstruktur von (pp3)RuH(C6H4CF3-3) (pp3 = P(CH2CH2CH2PMe2)3)
Dahlenburg, L.,Frosin, K.-M.,Kerstan, S.,Werner, D.
, p. 115 - 124 (1991)
The complexes L4RuH(C6H5) with L4 = P(CH2CH2CH2PMe2)3, N(CH2CH2PPh2)3, and MeSi(CH2PMe2)3/PMe3 all serve as catalysts for the dimerization of 1-alkynes, RCCH (R = C6H5, n-C4H9, t-C4H9).The reaction proceeds to yield 1,4-disubstituted 1-en-3-ynes.RCH=CH
