Oligophosphan-Liganden XXXII. Katalytische Dimerisierung von 1-Alkinen zu linearen 1-En-3-inen an cis-Arylhydridoruthenium(II)Chelatkomplexen. Molekuelstruktur von (pp3)RuH(C6H4CF3-3) (pp3 = P(CH2CH2CH2PMe2)3)

DOI: 10.1016/0022-328X(91)83145-T

Source and publish data:

Journal of Organometallic Chemistry p. 115 - 124 (1991)

Update date:2022-08-05

Topics:

Authors:

Dahlenburg, L.

Frosin, K.-M.

Kerstan, S.

Werner, D.

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Article abstract of DOI:10.1016/0022-328X(91)83145-T

The complexes L4RuH(C6H5) with L4 = P(CH2CH2CH2PMe2)3, N(CH2CH2PPh2)3, and MeSi(CH2PMe2)3/PMe3 all serve as catalysts for the dimerization of 1-alkynes, RC<*>CH (R = C6H5, n-C4H9, t-C4H9).The reaction proceeds to yield 1,4-disubstituted 1-en-3-ynes.RCH=CH

Full text of DOI:10.1016/0022-328X(91)83145-T

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Product name:(k⁴-N(CH₂CH₂PPh₂)₃)RuCl₂

Cas No:85436-56-2

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