85475-95-2

Upstream product

• 3559-72-6 1,1-dichloro-2-phenylthioethene 
• 108-98-5 thiophenol 
• 88388-87-8 C₁₄H₁₀Cl₂S₂ 
• 811-97-2 1,1,1,2-tetrafluoroethane 
• 63139-23-1 phenylthioethynyl trimethylsilane 
• 6228-98-4 phenylthioacetylene 
• 882-33-7 diphenyldisulfane 
• 129540-75-6 oxy>iodo>benzene 
• 52060-25-0 2,2,2-Trichlor-1,1-bis-phenylmercapto-ethan 
• 930-69-8 sodium thiophenolate 
• 129540-78-9 bisoxy>iodo>acetylene 

Downstream Products

• 109458-96-0 8-Chloro-1-methyl-6,7-bis-phenylsulfanyl-bicyclo[3.2.1]oct-6-ene 
• 134840-57-6 Bis(phenylsulphonyl)acetylene 
• 97760-26-4 2,3-bis(phenylsulfonyl)bicyclo[2.2.1]hepta-2,5-diene 
• 134840-59-8 2-Benzenesulfinyl-3-benzenesulfonyl-bicyclo[2.2.1]hepta-2,5-diene 
• 134840-60-1 (1R,2S,4R,5S)-6,7-Bis-benzenesulfonyl-3-oxa-tricyclo[3.2.1.0^2,4]oct-6-ene 
• 139-66-2 diphenyl sulfide 
• 108-98-5 thiophenol 
• 95-15-8 Benzo[b]thiophene 
• 92-85-3 Thianthrene 
• 71-43-2 benzene 
• 121738-10-1 C₁₉H₁₉ClS₂ 
• 588-59-0 stilbene 
• 409105-50-6 (η(5)-cyclopentadienyl)-[η(4)-1,2-bis(tert-butylsulfonyl)-3,4-bis(phenylthio)cyclobutadiene]cobalt(I) 
• 409105-51-7 (η(5)-methylcyclopentadienyl)-[η(4)-1,2-bis(tert-butylsulfonyl)-3,4-bis(phenylthio)cyclobutadiene]cobalt(I) 

Relevant academic research and scientific papers

Facile 1,1-carboboration reactions of acetylenic thioethers

The acetylenic thioether PhSCi - CSPh undergoes a rapid 1,1-carboboration reaction with facile -SPh migration upon treatment with B(C6F5)3 to yield the borylated ketene dithioacetal product (PhS)2C=C(C6/su

Solvolytically DMSO-promoted reactions of 1,1,1-trifluoroethyl chloride (HCFC-133a) or fluoride (HFC-134a) with nucleophiles

Fluorinated gases HCFC-133a (CF3CH2Cl, bp=6°C) and HFC-134a (CF3CH2F, bp=-27°C) are found highly soluble in DMSO. In their DMSO solutions, oxygen-, nitrogen- and sulfur-nucleophilic reactions may occur in normal

A New Approach to the Synthesis of Symmetrical Bis(organylchalcogeno)acetylenes: Scope and Limitations

A new general method to prepare bis(organylchalcogeno)acetylenes R-Y-CC-Y-R (Y = S, Se, Te) by dehydrochlorination of the corresponding 1,2-bis(organylchalcogeno)chloroethylenes R-Y-CH=CCl-Y-R with tert-BuOK/tert-BuOH and/or KOH/DMSO is developed.Dechlorination of 1,2-bis(organylchalcogeno)-1,2-dichloroethylenes R-Y-CCl=CCl-Y-R (Y = S, Se, Te) with BuLi in ether or THF is effective only for sulfur derivatives.With Y = Se and alkyl substituents, substitution of the chlorine atom by a butyl group takes place giving rise to 5,6-bis(alkylseleno)dec-5-ene .With aryl substituents, an attack of the ArSe-group by the Bu-radical is observed leading to an aryl butyl selenide.In the case of the tellurium compound Ph-Te-CCl=CCl-Te-Ph, there is a competition between dechlorination to give Ph-Te-CC-Te-Ph, and substitution to produce the phenyl butyl telluride. - Keywords: bis(organylchalcogeno)acetylene; 1,2-bis(organylchalcogeno)chloroethylene; 1,2-bis(organochalcogeno)-1,2-dichloroethylene.

Preparation and Chemistry of PhI+C≡CI+Ph·2-OTf, Bis[phenyl[[(trifluoromethyl)sulfonyl]oxy]iodo]acetylene, a Novel Difunctional Acetylene, Bis(iodonium) Species and a Stable C2-Transfer Agent

The title compound 2 is readily prepared as a stable microcrystalline solid from bis(tri-/i-butylstannyl)acetylene and PhICN-OTf. It was fully characterized by multinuclear NMR, IR, and elemental analysis. As expected, the electron-deficient acetylene 2 r

Reactions of 2,2-Dichlorovinyl and 2,2-Dichlorovinylidene Sulfides with Butyllithium

The present paper describes the reactions of two series of compounds, RS(R'S)C=CCl2 and RS(R')C=CCl2, with butyllithium.The former gives 1,2-dithio-substituted acetylenes by rearrangement, whereas the latter gives cumulenes by dimerization. Keywords --- 2