854759-71-0Relevant articles and documents
Formal enantioselective synthesis of aplykurodinone-1
Peixoto, Philippe A.,Jean, Alexandre,Maddaluno, Jacques,De Paolis, Michael
, p. 6971 - 6973 (2013)
Step economy and simplicity were combined in the asymmetric formal synthesis of aplykurodinone-1 (see scheme; TBS=tert-butyldimethylsilyl). The key features of the strategy involve a one-pot aerobic and directed oxidation/deoxygenation and a late-stage co
Formal total synthesis of (+)-wortmannin using catalytic asymmetric intramolecular aldol condensation reaction
Shigehisa, Hiroki,Mizutani, Takashi,Tosaki, Shin-Ya,Ohshima, Takashi,Shibasaki, Masakatsu
, p. 5057 - 5065 (2007/10/03)
A catalytic process for the synthesis of optically active C4-substituted tetrahydroindandiones using an asymmetric intramolecular aldol condensation reaction was developed. When 30 mol% of phenylalanine and 50 mol% of pyridinium p-toluenesulfonate were us