854764-44-6Relevant articles and documents
Enantioselective synthesis of 1-(R)-hydroxypolygodial and its 9α epimer, 1-(R)-hydroxyisotadeonal
Della Monica, Carmela,Della Sala, Giorgio,Izzo, Irene,De Petrocellis, Luciano,di Marzo, Vincenzo,Spinella, Aldo
, p. 6866 - 6873 (2007)
The enantioselective synthesis of 1-(R)-hydroxypolygodial and its epimer at C-9 is described. α-Ionone was the starting material. Key steps of these syntheses included a Corey-Bakshi-Shibata oxazaborolidine-mediated reduction and a stereoselective Diels-A
Enantioselective synthesis of 1(R)-hydroxypolygodial
Della Monica, Carmela,Della Sala, Giorgio,D'Urso, Deborah,Izzo, Irene,Spinella, Aldo
, p. 4061 - 4063 (2007/10/03)
Enantioselective preparation of 1(R)-hydroxypolygodial (5) has been achieved starting from α-ionone through a synthetic strategy involving a Corey-Bakshi-Shibata oxazaborolidine-mediated reduction and a stereoselective Diels-Alder reaction as key steps.