855342-02-8

Basic information

• Product Name: (2-{4-[(E)-2-(4-{(E)-2-[4-(2-Dimethylamino-ethoxy)-phenyl]-vinyl}-phenyl)-vinyl]-phenoxy}-ethyl)-dimethyl-amine
• Synonyms: (2-{4-[(E)-2-(4-{(E)-2-[4-(2-Dimethylamino-ethoxy)-phenyl]-vinyl}-phenyl)-vinyl]-phenoxy}-ethyl)-dimethyl-amine
• CAS NO: 855342-02-8
• Molecular Weight: 456.628
• Mol File: 855342-02-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-{4-[(E)-2-(4-{(E)-2-[4-(2-Dimethylamino-ethoxy)-phenyl]-vinyl}-phenyl)-vinyl]-phenoxy}-ethyl)-dimethyl-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (2-{4-[(E)-2-(4-{(E)-2-[4-(2-Dimethylamino-ethoxy)-phenyl]-vinyl}-phenyl)-vinyl]-phenoxy}-ethyl)-dimethyl-amine(855342-02-8)
• EPA Substance Registry System: (2-{4-[(E)-2-(4-{(E)-2-[4-(2-Dimethylamino-ethoxy)-phenyl]-vinyl}-phenyl)-vinyl]-phenoxy}-ethyl)-dimethyl-amine(855342-02-8)

Safety Data

• Hazardous Substances Data: 855342-02-8(Hazardous Substances Data)

Upstream product

• 15182-92-0 4-(2-dimethylaminoethoxy)benzaldehyde 
• 4546-04-7 tetraethyl 1,4-xylylenediphosphonate 
• 623-24-5 1,4-bis(bromomethyl)benzene 

Relevant articles and documents

Nanostructured oligo(p-phenylene vinylene)/silicate hybrid films: One-step fabrication and energy transfer studies

Novel hybrid materials containing silicate and charged oligo(p-phenylene vinylene) (OPV) amphiphiles were fabricated in one step by spin casting using evaporation-induced self assembly. The conjugated segments were substituted with trimethylammonium bromide groups at both termini, and tetraethyl orthosilicate served as the silicate precursor. X-ray diffraction scans of the hybrid films revealed Bragg diffraction peaks with d-spacings of 2.76 and 1.37 nm, indicating the presence of order in the hybrid structure. Optical properties of the hybrid films were characterized by UV-vis absorption and fluorescence spectra, and molecular orientation was characterized by IR spectroscopy. A rhodamine B derivative containing a triethoxysilane group was covalently incorporated into the silicate network of the films during the sol-gel reaction. Relative to disordered polymer films with identical organic composition, the ordered hybrid films revealed significantly enhanced emission from rhodamine B and also fluorescence quenching from OPV segments. These results indicate that the ordered and nanostructured environment leads to highly efficient energy transfer among organic components in these hybrid films.