85558-84-5Relevant academic research and scientific papers
POLAR EFFECTS IN FREE-RADICAL REACTIONS. A NEW TYPE OF HOMOLYTIC AROMATIC ALKYLATION BY SILVER CATALYZED OXIDATION OF ACETONE BY PEROXYDISULPHATE IN THE PRESENCE OF OLEFINS.
Citterio, Attilio,Gentile, Anna,Minisci, Francesco
, p. 5587 - 5590 (1982)
Silver catalyzed peroxydisulphate oxidation of acetone in the presence of olefins and protonated heteroaromatic bases leads to compound I via addition of acetonyl radical to the olefin and scavenging of the resulting radical adduct by the aromatic base.
