855749-08-5

Basic information

• Product Name: N-(2-(cyclohexenylethynyl)phenyl)-N-ethynyl-4-methylbenzenesulfonamide
• Synonyms: N-(2-(cyclohexenylethynyl)phenyl)-N-ethynyl-4-methylbenzenesulfonamide
• CAS NO: 855749-08-5
• Molecular Weight: 375.491
• Mol File: 855749-08-5.mol

Chemical Properties

• CAS DataBase Reference: N-(2-(cyclohexenylethynyl)phenyl)-N-ethynyl-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-(cyclohexenylethynyl)phenyl)-N-ethynyl-4-methylbenzenesulfonamide(855749-08-5)
• EPA Substance Registry System: N-(2-(cyclohexenylethynyl)phenyl)-N-ethynyl-4-methylbenzenesulfonamide(855749-08-5)

Safety Data

• Hazardous Substances Data: 855749-08-5(Hazardous Substances Data)

Upstream product

• 855749-01-8 N-(2-(cyclohex-1-en-1-ylethynyl)phenyl)-4-methylbenzenesulfonamide 
• 133816-00-9 phenyl(trimethylsilylethynyl)iodonium triflate 
• 288254-64-8 2-(cyclohex-1-en-1-ylethynyl)aniline 
• 615-43-0 2-iodophenylamine 
• 931-49-7 1-ethenylcyclohexene 

Relevant articles and documents

Gold(I)-catalyzed 1,2-acyloxy migration/[3+2] cycloaddition of 1,6-diynes with an ynamide propargyl ester moiety: Highly efficient synthesis of functionalized cyclopenta[b]indoles

A gold-catalyzed cycloisomerization of 1,6-diynes containing an ynamide propargyl ester or carbonate moiety has been developed that provides an attractive route to a diverse-substituted 3-acyloxy-1,4-dihydrocyclopenta[b]indoles. Mechanistic studies indicate that the reaction likely proceeds through a competitive 1,2-OAc migration followed by [3+2] cycloaddition of the vinyl gold-carbenoid intermediate with the pendant triple bond. The synthetic utility of the obtained cyclopenta[b]indole products was demonstrated by their efficient transformations by deprotection or double-bond isomerization reactions.

Synthesis of carbazoles by dehydro Diels-Alder reactions of ynamides

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Synthesis of carbazoles from ynamides by intramolecular dehydro Diels-Alder reactions

(Chemical Equation Presented) A new approach to carbazoles and benzannulated carbazoles by means of intramolecular dehydro Diels-Alder reactions of ynamides is reported. By using this approach, carbazoles and benzo[b]-, tetrahydrobenzo[b]-, naphtho[1,2-b]