856015-17-3

Basic information

• Product Name: (R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-piperidine
• Synonyms: (R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-piperidine
• CAS NO: 856015-17-3
• Molecular Weight: 353.58
• Mol File: 856015-17-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-piperidine(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-piperidine(856015-17-3)
• EPA Substance Registry System: (R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-piperidine(856015-17-3)

Safety Data

• Hazardous Substances Data: 856015-17-3(Hazardous Substances Data)

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 3197-44-2 (2R)-piperidin-2-ylmethanol 
• 220223-44-9 4-(tert-Butoxycarbonyl-methoxycarbonylmethyl-amino)-butyric acid methyl ester 
• 220223-47-2 (2S,3S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-3-(imidazole-1-carbothioyloxy)-piperidine-1-carboxylic acid tert-butyl ester 
• 150779-88-7 (2S,3S)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-3-hydroxy-piperidine-1-carboxylic acid tert-butyl ester 
• 122019-53-8 3-oxo-1,2-piperidinedicarboxylic acid 1-(1,1-dimethylethyl) 2-methyl ester 
• 152230-79-0 (2R,3S)-1-tert-butyloxycarbonyl-2-methoxycarbonyl-3-hydroxy-piperidine 
• 150779-89-8 (2S,3S)-tert-butyl 3-hydroxy-2-(hydroxymethyl)piperidine-1-carboxylate 
• 18650-38-9 (R)-piperidine-2-carboxylic acid methyl ester hydrochloride 
• 150779-90-1 tert-butyl (R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)piperidine-1-carboxylate 

Downstream Products

• 60343-64-8 (R)-(1-tosylpiperidin-2-yl)methanol 
• 150779-99-0 (R)-2-(tert-Butyl-diphenyl-silanyloxymethyl)-1-(toluene-4-sulfonyl)-piperidine 

Relevant articles and documents

A formal [3 + 3] cycloaddition reaction. 5. An enantioselective intramolecular formal aza-[3 + 3] cycloaddition reaction promoted by chiral amine salts

A detailed account on chiral secondary amine salt promoted enantioselective intramolecular formal aza-[3 + 3] cycloadditions is described here for the first time. The dependence of enantioselectivity on the structural feature of these chiral amines is tho

New Members of the Chiral Pool: β-Hydroxypiperidine Carboxylates from Baker's Yeast Reduction of the Corresponding Keto-esters

Baker's yeast reductions of the keto-piperidinecarboxylates 2 and 6 leads to the corresponding hydroxy-esters 3 and 7a in good chemical yields and with >99percent d.e. and >93percent e.e. in both cases.