85630-17-7

Basic information

• Product Name: Carbamic acid, diethyl-, 3-methoxyphenyl ester
• CAS NO: 85630-17-7
• Molecular Formula: C12H17NO3
• Molecular Weight: 223.272
• Mol File: 85630-17-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Carbamic acid, diethyl-, 3-methoxyphenyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, diethyl-, 3-methoxyphenyl ester(85630-17-7)
• EPA Substance Registry System: Carbamic acid, diethyl-, 3-methoxyphenyl ester(85630-17-7)

Safety Data

• Hazardous Substances Data: 85630-17-7(Hazardous Substances Data)

Upstream product

• 88-10-8 N,N-diethylcarbamyl chloride 
• 108-46-3 recorcinol 
• 150-19-6 O-methylresorcine 
• 75-44-5 phosgene 

Downstream Products

• 1225288-09-4 O-(2-iodo-5-methoxy)phenyl N,N-diethylcarbamate 
• 10040-94-5 1-(3-methoxyphenyl)-1H-imidazole 
• 889361-55-1 1-(triisopropylsilyl)-2-(3-methoxyphenyl)ethyne 
• 404377-69-1 2-(3-methoxyphenyl)-5-methyl-1,3-benzoxazole 
• 121980-50-5 2-iodo-3-(methyloxy)phenol 
• 1445899-08-0 2-hydroxy-5-methoxyphenyl diethylcarbamate 
• 1453186-32-7 (E)-methyl 3-(2-((diethylcarbamoyl)oxy)-4-methoxyphenyl)acrylate 
• 1417448-17-9 (E)-ethyl 3-(2-((diethylcarbamoyl)oxy)-4-methoxyphenyl)but-2-enoate 
• 1259161-77-7 C₁₂H₁₆ClNO₃ 
• 1245824-42-3 5-methoxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl N,N-diethylcarbamate 
• 1245728-71-5 3-methoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl diethylcarbamate 
• 85630-30-4 N,N-diethyl-2-hydroxy-6-methoxybenzamide 

Relevant articles and documents

N -Arylation of (hetero)arylamines using aryl sulfamates and carbamates via C-O bond activation enabled by a reusable and durable nickel(0) catalyst

An effective and general aryl amination protocol has been developed using a magnetically recoverable Ni(0) based nanocatalyst. This new stable catalyst was prepared on Fe3O4@SiO2 modified by EDTA and investigated by FT-IR, EDX, TEM, XRD, DLS, FE-SEM, XPS, NMR, TGA, VSM, ICP and elemental analysis techniques. The reaction proceeded via carbon-oxygen bond cleavage of (hetero)aryl carbamates and sulfamates under simple and mild conditions without the use of any external ligands. This method demonstrated functional group tolerance in the N-arylation of various nitrogen-containing compounds as well as aliphatic amines, anilines, pyrroles, pyrazoles, imidazoles, indoles, and indazoles with good to excellent yields. Furthermore, the catalyst could be easily recovered by using an external magnetic field and directly reused at least six times without notable reduction in its activity. This journal is

Directed ortho-Metalation of Aryl Amides, O-Carbamates, and Methoxymethoxy Systems: Directed Metalation Group Competition and Cooperation

A systematic study on the competitive metalation of derivatives containing four directed metalation groups (DMGs), namely, Cl, OMe, methoxymethoxy (OMOM), and CONEt2, in comparison with the OCONEt2 DMG is described. In addition, the

Double heteroatom functionalization of arenes using benzyne three-component coupling

Arynes participate in three-component coupling reactions with N, S, P, and Se functionalities to yield 1,2-heteroatom-difunctionalized arenes. Using 2-iodophenyl arylsulfonates as benzyne precursors, we could effectively add magnesiated S-, Se-, and N-nucleophilic components to the strained triple bond. In the same pot, addition of electrophilic N, S, or P reagents and a copper(I) catalyst trapped the intermediate aryl Grignard to produce a variety of 1,2- difunctionalized arenes.