856406-49-0Relevant articles and documents
New syntheses of 3-aroylflavone derivatives; Knoevenagel condensation and oxidation versus one-pot synthesis
Vaz, Patrícia A. A. M.,Pinto, Diana C. G. A.,Rocha, Djenisa H. A.,Silva, Artur M. S.,Cavaleiro, José A. S.
, p. 2353 - 2356 (2013/07/19)
Two syntheses of 3-aroylflavones have been established. In the first synthesis the use of microwave irradiation led to an improvement in the yields of both the Knoevenagel condensation of β-diketones with aldehydes to afford 3-aroylflavanones and of their
Baker-venkataraman rearrangement under microwave irradiation: A new strategy for the synthesis of 3-aroyl-5-hydroxyflavones
Pinto, Diana C. G. A.,Silva, Artur M. S.,Cavaleiro, José A. S.
, p. 1897 - 1900 (2008/03/13)
Microwave irradiation selectively induces the Baker-Venkataraman rearrangement of 2′,6′-diaroyloxyacetophenones to give 3-aroyl-5-hydroxyflavones, in a very short reaction time. Under classical heating conditions these reactions afforded 5-hydroxyflavones