85657-31-4Relevant academic research and scientific papers
Claisen rearrangements. X. Synthesis of the coumarins, hortiolone and hortinone
Murray,Jorge,Lawrie
, p. 3159 - 3162 (1983)
The linear furanocoumarin, hortiolone 1 from Hortia arborea has been synthesised in five steps from 7-hydroxy-5-prenyloxycoumarin in 76% overall yield. The spectroscopic evidence for the co-occurring hortinone has been reassessed and the revised angular furanocoumarin structure 9 confirmed by synthesis.
SYNTHESIS OF THE COUMARIN, HORTIOLONE
Murray, R. D. H.,Jorge, Z. D.,Lawrie, K. W. M.
, p. 4847 - 4848 (2007/10/02)
The structure of the natural coumarin, hortiolone, has been confirmed by a total synthesis in 6 steps from 5,7-diacetoxycoumarin in 48percent overall yield.
