Claisen rearrangements. X. Synthesis of the coumarins, hortiolone and hortinone

DOI: 10.1016/S0040-4020(01)91559-5

Source and publish data:

Tetrahedron p. 3159 - 3162 (1983)

Update date:2022-08-04

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Authors:

Murray Murray

Jorge Jorge

Lawrie Lawrie

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Article abstract of DOI:10.1016/S0040-4020(01)91559-5

The linear furanocoumarin, hortiolone 1 from Hortia arborea has been synthesised in five steps from 7-hydroxy-5-prenyloxycoumarin in 76% overall yield. The spectroscopic evidence for the co-occurring hortinone has been reassessed and the revised angular furanocoumarin structure 9 confirmed by synthesis.

Full text of DOI:10.1016/S0040-4020(01)91559-5

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