856591-70-3 Usage
General Description
2-(2-furylmethylsulfanyl)pyridine is a chemical compound with the molecular formula C11H9NOS. It consists of a pyridine ring with a sulfur atom and a furan ring attached to it, forming a thioether and an ether linkage, respectively. 2-(2-furylmethylsulfanyl)pyridine is used in organic synthesis and pharmaceutical research due to its ability to act as a ligand in coordination chemistry and its potential biological activities. The compound has been studied for its potential applications in pharmaceuticals, including its antimicrobial and anticancer properties. Additionally, it is used as a building block in the synthesis of various heterocyclic compounds.
Check Digit Verification of cas no
The CAS Registry Mumber 856591-70-3 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,5,6,5,9 and 1 respectively; the second part has 2 digits, 7 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 856591-70:
(8*8)+(7*5)+(6*6)+(5*5)+(4*9)+(3*1)+(2*7)+(1*0)=213
213 % 10 = 3
So 856591-70-3 is a valid CAS Registry Number.
856591-70-3Relevant articles and documents
Versatile C(sp2)?C(sp3) Ligand Couplings of Sulfoxides for the Enantioselective Synthesis of Diarylalkanes
Dean, William M.,?iau?iulis, Mindaugas,Storr, Thomas E.,Lewis, William,Stockman, Robert A.
supporting information, p. 10013 - 10016 (2016/08/16)
The reaction of chiral (hetero)aryl benzyl sulfoxides with Grignard reagents affords enantiomerically pure diarylalkanes in up to 98 % yield and greater than 99.5 % enantiomeric excess. This ligand coupling reaction is tolerant to multiple substitution patterns and provides access to diverse areas of chemical space in three operationally simple steps from commercially available reagents. This strategy provides orthogonal access to electron-deficient heteroaromatic compounds, which are traditionally synthesized by transition metal catalyzed cross-couplings, and circumvents common issues associated with proto-demetalation and β-hydride elimination.