85670-55-9Relevant academic research and scientific papers
Stereoselective Cross-Aldol Reactions of Silyl Enol Ethers with Acetals Catalyzed by Iodotrimethylsilane
Sakurai, Hideki,Sasaki, Koshi,Hosomi, Akira
, p. 3195 - 3196 (1983)
Iodotrimethylsilane catalyzes effectively erythroselective aldol type condensation of silyl enol ethers with acetals.
NOUVELLE SYNTHESE REGIOSELECTIVE DE β-ALCOXYCETONES A PARTIR D'ENOXYSILANES ET DE TRISENOXYSILANES ENGENDRES in situ
Rochin, Christophe,Babot, Odile,Duboudin, Francoise
, p. C24 - C28 (2007/10/02)
An easy, regiospecific, route to β-alkoxyketones based on the use of methyl trichlorosilane for in situ generation of α-chloroethers and trisenoxysilanes is described.
TRITYL PERCHLORATE AS AN EFFICIENT CATALYST IN THE ALDOL-TYPE REACTION
Mukaiyama, Teruaki,Kobayashi, Shu,Murakami, Masahiro
, p. 1759 - 1762 (2007/10/02)
In the presence of a catalytic amount of trityl perchlorate, silyl enol ethers and ketene silyl acetals react with acetals and methyl orthoformate to give the corresponding aldol-type addition products in good yields.
REACTIONS OF α-HETEROATOM-SUBSTITUTED ETHERS AND SULFIDES WITH SILYL ENOL ETHERS. CHEMOSELECTIVITY IN THE CLEAVAGE OF HETEROATOM-CARBON BONDS BY IODOTRIMETHYLSILANE AND TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE
Hosomi, Akira,Sakata, Yasuyuki,Sakurai, Hideki
, p. 405 - 408 (2007/10/02)
Reactions of α-heteroatom substituted ethers and related compounds (R1R2CXY; X, Y = RO, RS and Cl) with silyl enol ethers and ketene silyl acetals took place in the presence of iodotrimethylsilane (Ia) and trimethylsilyl triflate (Ib) as a catalyst and factors influencing the activation of the heteroatom by I were examined.
