85678-41-7

Upstream product

• 108-98-5 thiophenol 
• 177274-66-7 1-phenylsulfonyl-3-bromo-2-methylindole 
• 920-39-8 isopropylmagnesium bromide 
• 85678-42-8 2-(bromomethyl)-3-(phenylthio)-1-(phenylsulfonyl)-1H-indole 
• 56366-45-1 2-methyl-3-phenylthioindole 
• 98-09-9 benzenesulfonyl chloride 

Downstream Products

• 80360-21-0 1-(benzenesulfonyl)-2-methyl-1H-indole 
• 177274-67-8 3-bromo-2-(bromomethyl)-1-(phenylsulfonyl)-1H-indole 
• 177274-68-9 N-((3-bromo-1-(phenylsulfonyl)-1H-indol-2-yl)methyl)benzenesulfonamide 
• 177274-70-3 N-allyl-N-((3-bromo-1-(phenylsulfonyl)-1H-indol-2-yl)methyl)benzenesulfonamide 
• 1150615-89-6 1-phenylsulfonyl-2-methyl-3-(phenylsulfinyl)indole 
• 85678-46-2 1-Benzenesulfonyl-2-morpholin-4-ylmethyl-3-phenylsulfanyl-1H-indole 
• 85678-45-1 1-Benzenesulfonyl-3-phenylsulfanyl-2-piperidin-1-ylmethyl-1H-indole 
• 85678-44-0 1-Benzenesulfonyl-3-phenylsulfanyl-2-pyrrolidin-1-ylmethyl-1H-indole 
• 85678-43-9 (1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl)-dimethyl-amine 
• 85678-51-9 1-Benzenesulfonyl-2-morpholin-4-ylmethyl-1H-indole 
• 85678-50-8 1-Benzenesulfonyl-2-piperidin-1-ylmethyl-1H-indole 
• 85678-49-5 1-Benzenesulfonyl-2-pyrrolidin-1-ylmethyl-1H-indole 
• 85678-48-4 (1-Benzenesulfonyl-1H-indol-2-ylmethyl)-dimethyl-amine 
• 85678-47-3 Dimethyl-(3-phenylsulfanyl-1H-indol-2-ylmethyl)-amine 

Relevant academic research and scientific papers

Facile preparation of indolyl-2/3-methylsulfoxides using HF/H 2O2

A variety of indolyl-2/3-methylsulfides tethered with sensitive functionalities were oxidized to the corresponding sulfoxides using a hitherto unexplored HF/H2O2 system. Copyright Taylor & Francis Group, LLC.

Unusual dimerization of N-protected bromomethylindoles/benzyl bromide with arylmetal halides: generation of indolylmethyl/benzyl radical

A detailed study on the interaction of N-protected bromomethylindoles with various types of aryl/alkyl Grignard is reported. Full experimental details on the mechanism of the unusual dimerization reaction are presented.

Pyridinophanes as two-centre phase-transfer catalyst for N-alkylation reaction

The synthetic utility of water-soluble pyridinophanes 1 and 2 as an efficient two-centre phase-transfer catalyst for N-alkylation of indoles, imidazole, benzimidazole and benzotriazole has been explored. Application of such pyridinophanes for the synthesis of various precyclophanes involving bis-N alkylation is also described. Georg Thieme Verlag Stuttgart.

Unusual dimerization of N-protected bromomethylindoles using phenylmagnesium chloride

A novel dimerization of N-protected bromomethylindoles involving an exchange reaction with phenylmagnesium chloride is reported.

A Facile Preparation of N-Benzensulphonylindoles Using Phase Transfer Catalyst

Treatment of an indole with benzenesulphonyl chloride in bezene - 50percent aq. sodium hydroxide solution in the presence of cetyltrimethylammonium bromide affords the corresponding N-benzenesulphonylindoles in 60-70percent yield.