85686-13-1

Upstream product

• 124-38-9 carbon dioxide 
• 1698-98-2 Brenzcatechindi-isopropylether 
• 303-38-8 2,3-Dihydroxybenzoic acid 
• 75-26-3 isopropyl bromide 
• 2411-83-8 methyl-2,3-dihydroxybenzoate 
• 114605-64-0 methyl 2,3-di-isopropoxybenzoate 

Downstream Products

• 114605-65-1 2,3-Diisopropoxy-benzoyl chloride 
• 1416579-58-2 (R)-tert-butyl 5-(((benzyloxy)carbonyl)amino)-2-(2,3-diisopropoxybenzamido)pentanoate 
• 1416579-62-8 (R)-methyl 5-(((benzyloxy)carbonyl)amino)-2-(2,3-diisopropoxybenzamido)pentanoate 
• 1416579-54-8 N-4-aminobutyl-2,3-diisopropoxybenzamide 
• 1416579-55-9 N-(4-(2-chloroacetamido)butyl)-2,3-diisopropoxybenzamide 
• 1416579-59-3 (R)-tert-butyl 5-amino-2-(2,3-diisopropoxybenzamido)pentanoate 
• 1416579-60-6 (R)-tert-butyl 5-(2-chloroacetamido)-2-(2,3-diisopropoxybenzamido)pentanoate 
• 1416579-63-9 (R)-5-(((benzyloxy)carbonyl)amino)-2-(2,3-diisopropoxybenzamido)pentanoic acid 
• 1416579-56-0 C₃₅H₄₆FN₅O₇ 
• 1416579-49-1 C₂₉H₃₄FN₅O₇ 
• 1416579-61-7 C₄₀H₅₄FN₅O₉ 
• 1416579-51-5 C₃₀H₃₄FN₅O₉ 
• 1416579-64-0 C₃₇H₅₅N₃O₉ 
• 1416579-65-1 C₂₉H₄₉N₃O₇ 

Relevant academic research and scientific papers

Identification of the Ferric-Acinetobactin Outer Membrane Receptor in Aeromonas salmonicida subsp. salmonicida and Structure-Activity Relationships of Synthetic Acinetobactin Analogues

Aeromonas salmonicida subsp. salmonicida, the causative agent of furunculosis in several fish species, produces acinetobactin and amonabactin as siderophores. In a previous study, we chemically characterized these siderophores and proposed a biosynthetic

The Structure and Synthesis of the Novel Orchid Pigments Dengibsin and Dengibsinin

The structures of the orchid pigments dengibsin and dengibsinin have been revised to 2,5-dihydroxy-4-methoxy-9H-fluoren-9-one (4) and 3,5-dihydroxy-2,4-dimethoxy-9H-fluoren-9-one (5).The synthesis of these compounds is described.It has been found that 2'-methoxybiphenyl-2-carboxylic acids, on treatment with trifluoroacetic anhydride or oxalyl chloride, undergo cyclization giving 6H-dibenzopyran-6-ones.

STERIC EFFECTS IN THE METALLATION OF ALKOXY- AND DIALKOXY-BENZENES

With the aim of examining the role of steric factors in determining the position of metallation, the reaction of n-butyllithium with a series of 1,2-dialkoxy-, 1,2-alkylthio-, 1,4-dialkoxy-, and 2-t-butyl-1-alkoxy-benzenes has been studied in the presence and in the absence of N,N,N',N'-tetramethylethylenediamine (TMEDA).Steric factors are particularly relevant in the case of 2-t-butyl-alkoxybenzenes where the yields of metallation dramatically decrease passing from the methoxy to the isopropoxy derivative, while with the t-butoxy derivative only cleavage of the ether bond occurs.