85687-93-0Relevant academic research and scientific papers
Half-titanocene complexes bearing bulky dibenzhydryl-substituted aryloxide ligand: Syntheses, characterization, and ethylene (Co-)polymerization behaviors
Dong, Bo,Zhang, Hexin,Li, Hua,Liu, Heng,Guo, Jun,Zhang, Chunyu,Zhang, Xu,Hu, Yanming,Sun, Guangping,Zhang, Xuequan
, p. 188 - 193 (2016)
Three half-titanocene complexes 2a-3a bearing dibenzhydryl-substituted aryloxide ligands CpTiCl2(O-2,6-Ph2[Formula presented]6H2-4-Me), 2a; CpTiCl2 (O-2,6-Ph2[Formula presented]6
1-Mono- And 1,7-Disubstituted Perylene Bisimide Dyes with Voluminous Groups at Bay Positions- And Search for Highly Effective Solid-State Fluorescence Materials
Krause, Ana-Maria,Sü?, Jasmin,Schembri, Tim,Schmidt, David,Stolte, Matthias,Vysotsky, Myroslav O.,Würthner, Frank
, p. 6222 - 6236 (2020)
A series of 1-mono- and 1,7-disubstituted perylene bisimides (PBIs) with voluminous phenoxy groups at bay positions has been synthesized. These dyes show absorption and emission properties typical for PBIs in solution with high fluorescence quantum yields
An imido ligand significantly enhances the effective energy barrier of dysprosium(iii) single-molecule magnets
Liu, Bing-Cheng,Ge, Ning,Zhai, Yuan-Qi,Zhang, Tao,Ding, You-Song,Zheng, Yan-Zhen
supporting information, p. 9355 - 9358 (2019/08/08)
We report herein an imido ligand 1,3-bis(2,6-diisopropylphenyl) imidazolin-2-imine (ImDippNH) that can form a very short Dy-N bond (2.12 ?) with the dysprosium(iii) ion, which leads to a much larger effective energy barrier for magnetisation reversal (803 K) compared to the analogous alkoxide ligand (53 K). Moreover, we predict that a linear two-coordinate [Dy(ImDippN)2]+ complex may have an effective energy barrier larger than 4000 K.
Uranium(III) complexes with bulky aryloxide ligands featuring metal-arene interactions and their reactivity toward nitrous oxide
Franke, Sebastian M.,Tran, Ba L.,Heinemann, Frank W.,Hieringer, Wolfgang,Mindiola, Daniel J.,Meyer, Karsten
supporting information, p. 10552 - 10558 (2013/10/01)
We report the synthesis and use of an easy-to-prepare, bulky, and robust aryloxide ligand starting from inexpensive precursor materials. Based on this aryloxide ligand, two reactive, coordinatively unsaturated U(III) complexes were prepared that are maske
